Influence of dyes in oxidative stability of samples of biodiesel
DOI:
https://doi.org/10.20873/jbb.uft.cemaf.v3n4.santosKeywords:
Biodiesel, dye, quinizarin, antioxidants, tert-butylhydroquinone, oxidative stabilityAbstract
The feasibility of using the dyequinizarin (QNZ) on the oxidative stability of soybean biodiesel samples was studied in this work. The paper presents parameters indicative of the oxidation of biodiesel under thermal degradation through measurements of its acid value, peroxide and conjugated dienes and trienes. The study aimed to evaluate the behavior/performance antioxidant of the dyequinizarin (QNZ) along with the antioxidant tert – butylhydroquinone (TBHQ) at the concentration of 5mg L-1, iea possible synergism between these two substances. The samples were characterized by physicochemical analyzes and spectrophotometric UV/Vis(200-400 nm). The analysis of the acid number and peroxide were consistent with the absorbance at 232and 270nm, for in both analyzes were detected increase in the oxidation of biodiesel samples throughout storage period and/or thermal degradation.
References
Caires, A. R. L.; Lima, V. S.; Oliveira, S. L. (2012), Quantification of biodiesel content in diesel/biodiesel blends byfluorescence spectroscopy: Evaluation of the dependence on biodieselfeedstock. Renewable Energy, 46, 137-140.
Dabdoub, M.J.;Bronzel, J.L.; Rampin, M.A. (2009),Biodiesel: visão crítica do status atual e perspectivas na academia e na indústria. Química Nova, 32, 776-792.
Domingos, A. K.; Saad, E. B., Vechiatto, W. W. D.; Wilhelm, H. M.; Ramos, L. P. (2007), The influence of BHA, BHT and TBHQ on the oxidation stability of soybean oil ethyl esters (Biodiesel). JournaloftheBrazilianChemicalSociety, 18, 416-423.
Falcone, A. A. Avaliação da oxidação do biodiesel etílico de milho por meio de técnicas espectroscópias. Dissertação (Mestrado em Química) - Universidade Federal da Paraíba, 2007.
Ferrari, R. A. e Souza, W.L. (2009), Avaliação da estabilidade oxidativa de biodiesel de óleo de girassol com antioxidantes. Química Nova, 32, 106-111.
Ferrari, R. A.; Oliveira, V. S.; Scarbio, A. (2005),Biodiesel de soja-taxa de conversão em ésteres etílicos, caracterização físico-química e consumo em gerador de energia. Química Nova, 28, 19-23.
Filho, M. G. R. Cardanol e eugenol modificados - uso como antioxidantes no controle do processo oxidativo do biodiesel etílico de algodão. Tese (Doutorado em Química) -Universidade Federal da Paraíba, 2010.
Freitas, R. C. Biodiesel: O papel do estado regulador e formulador de políticas públicas. Dissertação (Mestrado em Engenharia de Transportes) -Universidade Federal do Rio de Janeiro, 2009.
Karavalakis, G. eStournas, S. (2010), Impact of antioxidant additives on the oxidation stability of diesel/biodiesel blends. Energy Fuels, 24, 3682-3686.
Knothe, G.; Gerpen, J.V.; Krahl, J. (2005), The biodiesel handbook. Illinois: AOCS Press, 303p.
Knothe, G. H. (2007),Some aspects of biodiesel oxidative stability. Fuel Processing Technology,88, 677-699.
Knothe, G.; Gerpen, J. V.; Krahl, J.; Ramos, L. P. (2006),Manual de Biodiesel, 1. Ed. São Paulo: Editora Blucher.
Liang, Y. C.; May, C. Y.; Foon, C. S.; Ngan, M. A.; Hock, C. C.; Basiron, Y. (2006), The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel. Fuel, 85, 867-870.
Massucatto, D. (2009), Investigação da cinética de lipase através da espectroscopia de fluorescência. Dissertação (Mestrado em Ciências) - Universidade de São Paulo, 2009.
Mazzeto, S.E.;Lomonaco, D.; Mele, G. (2009), Óleo da castanha de caju: oportunidades e desafios no contexto do desenvolvimento e sustentabilidade industrial. Química Nova, 32, 732-741.
Monteiro, M. R.; Ambrozini, A. R. P., Lião, L. M.; Ferreira, A. G. (2008),Criticalreviewonanalyticalmethods for biodiesel characterization. Talanta, 77, 593-605.
Monyem, A. e Van Gerpen, J.H. (2001),The effect of biodiesel oxidation on engine performance and emissions. BiomassandBioenergy,20, 317-325.
Quintella, C.M.; Teixeira, L. S. G.; Korn, M. G. A.; Neto, P. R. C.; Torres, E. A.; Castro, M. P.; Jesus, C. A. C. (2009), Cadeia do biodiesel da bancada à indústria: uma visão geral com prospecção de tarefas e oportunidades para P&D&I. Química Nova, 32, 793-808.
Shay, E.G. (1993),Diesel fuel from vegetable oils: status and opportunities. Biomass and Bioenergy, 4, 227-242.
Soares, C. M.; Itavo, L. C. V.; Dias, A. M.; Arruda, E. J.;Delben, A. A. S. T.; Oliveira, S. L.; Oliveira, L. C. S. (2010), Forage turnip, sunflower, and soybean biodiesel obtained by ethanol synthesis: Productionprotocols and thermal behavior. Fuel, 89, 3725-3729.
Tang, H.; De Guzman, R. C.; Simon, K. Y.; Salley, S. O. (2010), Effect of Antioxidants on the Storage Stability of Soybean-Oil-Based Biodiesel. Energy Fuels, 24, 2028 - 2033.
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 - Journal of Biotechnology and Biodiversity
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY 4.0 at http://creativecommons.org/licenses/by/4.0/) that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Authors are permitted and encouraged to post their work online (e.g. in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (Available at The Effect of Open Access, at http://opcit.eprints.org/oacitation-biblio.html).