Methylene blue dye adsorption study in pink kaolinite

Authors

DOI:

https://doi.org/10.20873/jbb.uft.cemaf.v2n3.leal

Keywords:

Adsorption, kaolinite, blue methylene

Abstract

This work aimed to study the adsorption of blue methylene dye using as adsorbent a kind of kaolinite called(named) pink kaolinite. The adsorbent was characterized from its chemical composition, by X-ray diffraction method and surface area by BET method. The variable parameters for the study in question were: the equilibrium time and the ratio of adsorbent mass per volume of adsorbate. It was found that the equilibrium time is less than 20 minutes and the highest adsorption occurred at 1:200 ratio, with a removal of 97%. The isotherm adsorption was constructed from the optimized kinetics adsorption parameters. The data were linearized for the models of Langmuir and Freundlich, and Langmuir model was that better explained the results.

References

Angove, M. J.; Johnson, B. B.; Wells, J. D. (1997), Adsorption of Cadimium (II) on kaolinite. Colloids and Surfaces A, 126, 137-147.

Baldez, E. E.; Robaina, N. F.; Cassella, R. J.(2008), Employment polyurethane foam for the adsorption of methylene blue in aqueous medium. Journal of Hazardous Materials, 159, 580-586.

Baskaralingam, P.; Pulikesi, M.; Ramamurthi, V.; Sivanesan, S. (2007), Modified hectorites and adsorption studies of a reactive dye. Applied Clay Scince, 37, 207-214.

Bharttachayya, K. G. and Gupta, S. S. (2008), Kaolinite and montmorillonite as adsorbents for Fe(III), Co(II) and Ni(II) in aqueous medium.Applied Clay Science, 41, 1-9.

Brady, V. P.; Cygan, T. R.; Nagy, L. K. (1996), Molecular Controls on Kaolinite Surface Charge. Journal of Colloid Interface Scince, 183, 356-364.

Castro, E. A. S. and Martins, J. B. L. (2005), Theoretical study of benzene interaction on kaolinite. Journal of Computer-Aided Materials Design, 12, 121-129.

Guerra D. L.; Souza, J. A.; Airoldi, C.; Viana, R. R. (2008), Avaliação da eficiência de caulinita intercalada com dimetilsulfóxido em adsorção com Zn(II) em meio aquoso – cinética do processo de adsorção. Cerâmica, 54, 273-279.

Harris, R. G.; Wells, J. D.; Johnson, B. B. (2001), Selective adsorption of dyes and other organic molecules to kaolinite and oxide surfaces. Colloids and Surface A, 180, 131-140.

Kunz, A.; Peralta-Zamora, P.; Moraes, S. G.; Durán, N. (2002), Novas tendências no tratamento de efluentes têxteis. Química Nova, 25, 78-82.

Lee,Y. S. and Kim, J. S. (2002), Adsorption of naphthalene by HDTMA modified kaolinite and halloysite. Applied Clay Science, 22, 55-63.

Leja, J. Surface chemistry of froth flotation. New York: Plenum Press, 1982.

Miranda-Trevino, J. C. and Coles, C. A. (2003), Kaolinite properties, structure and influence of metal retention on pH. Applied Clay Scince, 23, 133-139.

Nandi, B. K.; Goswami, A.; Purkait, M. K. (2008), Removal of cationic dyes from aqueous solutions by kaolin: Kinetic and equilibrium studies. Applied Clay Scince, 42, 583-591.

Neumann, M. G; Gessner, F; Cione A. P. P; Sartori A. R; Cavalheiro, S. C. C. (2000), Interações entre corantes e argilas em suspensão aquosa. Química Nova, 23, 818-824.

Pereira, E.; Oliveira, L. C. A.; Vallone, A.; Sapag, K. (2008), Preparação de carvão ativado em baixas temperaturas de carbonização a partir de rejeitos de café: utilização de FeCl3 como agente ativante. Química Nova, 31, 1296-1300.

Roulia, M. and Vassiliadis, A. A. (2008), Sorption characterization of a cationic dye retained by clays and perlite Microporus and Mesoporus Materials, 116, 732-740.

Silva, F. R. A. Avaliação de processosde adsorção de metais pesados: um estudo experimental com propostas de utilização de subprodutos. Dissertação (Mestrado em Sistemas de Gestão) - Universidade Federal Fluminense, 2005.

Tekin, N.; Demirbas, O.; Alkan, M. (2005), Adsorption of cationic polyacrylamide onto kaolinite. Microporous Mesoporous Materials, 85, 340-350.

Turak, F.; Ozgur, M.U.; Afsar, H. (2004), Use of natural and activated clay to remove methylene blue from aqueous solutions. In: 4th AACD Congress, Adnan Menderes University.

Unuabonah, E. I.; Adebowale, K. O.; Dawodu, F. A. (2008), Equilibrium, kinetic and sorber design studies on the adsorption of Aniline blue dye by sodium tetraborate-modified Kaolinite clay adsorbent. Journal of Hazardous Materials, 157, 397-409.

Vijayaraghavan, K.; Won, S. W.; Mao, J.; Yun, Y. (2008), Chemical modification of Corynebacterium glutamicum to improve methylene blue biosorption. Journal of Chemical Engineering, 145, 1-6.

Published

2011-08-08

How to Cite

Leal, P. V. B., dos Anjos, J. P., Magriotis, Z. M., Leal, P. V. B., Anjos, J. P. dos, & Magriotis, Z. M. (2011). Methylene blue dye adsorption study in pink kaolinite. Journal of Biotechnology and Biodiversity, 2(3), 38–42. https://doi.org/10.20873/jbb.uft.cemaf.v2n3.leal

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